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Rhodium carbonyl chloride : ウィキペディア英語版 | Rhodium carbonyl chloride
Rhodium carbonyl chloride is an organorhodium compound with the formula Rh2Cl2(CO)4. It is a red-brown volatile solid that is soluble in nonpolar organic solvents. It is a precursor to other rhodium carbonyl complexes, some of which are useful in homogeneous catalysis. ==Structure== The molecule consists of two planar Rh(I) centers linked by two bridging chloride ligands and four CO ligands. X-ray crystallography shows that the two Rh(I) centers are square planar with the dihedral angle of 53° between the two RhCl2 planes. The metals are nonbonding.〔Walz, Leonhard; Scheer, Peter "Structure of di-μ-chlorobis()" Acta Crystallographica, Section C: Crystal Structure Communications 1991, C47, 640-41. 〕
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